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Beilstein J. Nanotechnol. 2017, 8, 2139–2150, doi:10.3762/bjnano.8.213
Figure 1: Molecular structures of the molecules involved in the study and shortened forms of their names (in ...
Figure 2: a) STM constant height image (1.2 V, 1 nA) of a TMA–undecanol linear pattern (LP0) formed on HOPG (...
Figure 3: STM constant height image (1.2 V, 1 nA) of linear pattern LP4 (a), monoester type-I (c), and monoes...
Figure 4: STM constant current image (1.1 V, 1 nA) of TMA–monoundecyl ester type-I obtained from a TMA–undeca...
Figure 5: STM constant height images (1.2 V, 1.3 nA) of monoester obtained from a TMA–undecanol solution on H...
Figure 6: Simulation of the STM constant height mode images (HOMO (a) and LUMO (b)) of a single monoester mol...
Figure 7: STM constant height image (1.2 V, 1 nA) of the linear pattern of the synthesized monoester at the H...
Scheme 1: Proposed scheme of ester formation from TMA and undecanol via an intermediate dimer.
Figure 8: Energy diagram of the reaction path of TMA and undecanol to form TMA–undecyl ester and water for is...
Figure 9: Three possible hypotheses for the formation of the monoester from TMA and undecanol.
Beilstein J. Nanotechnol. 2017, 8, 1191–1204, doi:10.3762/bjnano.8.121
Figure 1: Chemical structures of porphyrins and metalloporphyrins successfully deposited by organic molecular...
Scheme 1: Synthetic methodology to prepare (metallo)porphyrins 2, 2a–d and 3, 3a–d.
Figure 2: IR spectra (KBr) in the range of 500–1800 cm−1 for H2TPP(CONMe2)4 (2, top) and MTPP(CONMe2)4 (MII =...
Figure 3: IR spectra (KBr) in the range of 500–1800 cm−1 for H2TPP(CON(iPr)2)4 (3, top) and MTPP(CON(iPr)2)4 ...
Figure 4: Left: UV–vis spectra (CHCl3, 280–700 nm) of H2TPP(C(O)NMe2)4 (2) and MTPP(C(O)NMe2)4 (MII = Zn, 2a ...
Figure 5: Top: TG traces of 3, 3b and 3d in comparison with H2TPP(OH)4. Bottom: TG traces of 2, 2c and 2d in ...